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Cost-effective customized wholesale 1',2',2'-TRIFLUOROSTYRENE 447-14-3
- Molecular Formula: C8H5 F3
- Molecular Weight: 158.123
- Melting Point: -23,5°C
- Refractive Index: 1.4741
- Boiling Point: 68°C 75mm
- Flash Point: 32.2°C
- PSA: 0.00000
- Density: 1.185g/cm3
- LogP: 3.22120
447-14-3 Relevant articles
TRIFLUOROVINYL DERIVATIVES OF ZINC AND TIN IN THE SYNTHESIS OF TRIFLUOROSTYRENES
Sorokina, R. S.,Rybakova, L. F.,Kalinovskii, I. O.,Beletskaya, I. P.
, p. 1506 - 1509 (1985)
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Solid-phase synthesis on functionalised fluoropolymer resins. Part 2: Preparation and properties of functional merrifieldtype resins possessing a perfluorinated polymer backbone
Liu, Shuyuan,Akhtar, Mahmoud,Gani, David
, p. 4493 - 4497 (2000)
Monomers α,β,β-trifluorostyrene and 4-me...
Synthesis method of aryl trifluoroethylene compound
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Paragraph 0037-0041; 0046-0081, (2021/04/10)
The invention belongs to the technical f...
Post-treatment method of trifluorostyrene synthesis liquid
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Paragraph 0020; 0034; 0056-0103, (2020/04/22)
The invention discloses a post-treatment...
Solvent- A nd anion-dependent rearrangement of fluorinated carbene ligands provides access to fluorinated alkenes
Hall, Lewis M.,Milner, Lucy M.,Hart, Sam J.,Whitwood, Adrian C.,Lynam, Jason M.,Slattery, John M.
supporting information, p. 17655 - 17659 (2019/12/23)
The construction of fluorocarbene ligand...
The organic group is substituted with a fluorine-containing olefin production
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Paragraph 0089; 0090; 0091; 0092; 0097; 0098; 0099; 0100, (2019/01/06)
PROBLEM TO BE SOLVED: To provide a produ...
447-14-3 Process route
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116-14-3,82785-14-6
polytetrafluoroethylene
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100-59-4
phenylmagnesium chloride
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-
447-14-3
1,2,2-trifluorostyrene
| Conditions | Yield |
|---|---|
|
With
tris-(dibenzylideneacetone)dipalladium(0); zinc(II) chloride; lithium iodide;
In
tetrahydrofuran; tetrahydrofuran-d8;
at 55 ℃;
for 8h;
under 2660.18 Torr;
Inert atmosphere;
Autoclave;
|
61%
|
|
With
zinc(II) chloride; lithium iodide;
tris-(dibenzylideneacetone)dipalladium(0);
In
tetrahydrofuran;
at 40 ℃;
for 18h;
under 2280.15 Torr;
Inert atmosphere;
|
44%
|
-
-
116-14-3,82785-14-6
polytetrafluoroethylene
-
-
2996-92-1,46143-12-8
phenyl trimethylsiloxane
-
-
447-14-3
1,2,2-trifluorostyrene
| Conditions | Yield |
|---|---|
|
With
tris-(dibenzylideneacetone)dipalladium(0); α,α,α-trifluorotoluene; tricyclohexylphosphine;
In
tetrahydrofuran-d8;
at 100 ℃;
for 2h;
under 2625.26 Torr;
Solvent;
Temperature;
Reagent/catalyst;
Glovebox;
Inert atmosphere;
|
85%
|
|
With
triethoxyfluorosilane; [Pd2(dba)3]*benzene; tricyclopentylphosphine;
In
tetrahydrofuran; tetrahydrofuran-d8;
at 80 ℃;
for 23h;
under 2660.18 Torr;
Reagent/catalyst;
Concentration;
Inert atmosphere;
|
94 %Spectr.
|
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