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3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-OL

  • CAS No.: 470-99-5
  • Purity: 99%
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Chemical plants supply high-quality 3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-OL 470-99-5 in bulk

  • Molecular Formula: C9H16O
  • Molecular Weight: 140.225
  • Appearance/Colour: clear colorless liquid 
  • Vapor Pressure: 0.161mmHg at 25°C 
  • Refractive Index: n20/D 1.472(lit.)  
  • Boiling Point: 188.9 °C at 760 mmHg 
  • PKA: 14.74±0.60(Predicted) 
  • Flash Point: 77.9 °C 
  • PSA: 20.23000 
  • Density: 0.915 g/cm3 
  • LogP: 2.11360 

3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-OL(Cas 470-99-5) Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 100, p. 2226, 1978 DOI: 10.1021/ja00475a040The Journal of Organic Chemistry, 47, p. 3311, 1982 DOI: 10.1021/jo00138a021

General Description

3,5,5-Trimethyl-2-cyclohexen-1-ol undergoes oxidation in the presence of palladium on activated charcoal under an ethylene atmosphere to yield the corresponding carbonyl compound.

InChI:InChI=1/C9H16O/c1-7-4-8(10)6-9(2,3)5-7/h4,8,10H,5-6H2,1-3H3/t8-/m1/s1

470-99-5 Relevant articles

Manganese-catalyzed homogeneous hydrogenation of ketones and conjugate reduction of α,β-unsaturated carboxylic acid derivatives: A chemoselective, robust, and phosphine-free in situ-protocol

Topf, Christoph,Vielhaber, Thomas

, (2021/07/10)

We communicate a user-friendly and glove...

BiCl3-Facilitated removal of methoxymethyl-ether/ester derivatives and DFT study of -O-C-O- bond cleavage

Pacherille, Angela,Tuga, Beza,Hallooman, Dhanashree,Dos Reis, Isaac,Vermette, Mélodie,Issack, Bilkiss B.,Rhyman, Lydia,Ramasami, Ponnadurai,Sunasee, Rajesh

supporting information, p. 7109 - 7116 (2021/05/03)

A simple method for the cleavage of meth...

A Practical and Stereoselective In Situ NHC-Cobalt Catalytic System for Hydrogenation of Ketones and Aldehydes

Zhong, Rui,Wei, Zeyuan,Zhang, Wei,Liu, Shun,Liu, Qiang

supporting information, p. 1552 - 1566 (2019/06/14)

Homogeneous catalytic hydrogenation of c...

Cerium-free Luche reduction directed by rehydrated alumina

Jones-Mensah, Ebenezer,Nickerson, Leslie A.,Deobald, Jackson L.,Knox, Hailey J.,Ertel, Alyssa B.,Magolan, Jakob

, p. 3748 - 3753 (2016/06/06)

A 1,2-regioselective reduction of α,β-un...

470-99-5 Process route

Phenyl vinyl ketone
768-03-6,26742-84-7

Phenyl vinyl ketone

phorone
504-20-1

phorone

isophorol
470-99-5

isophorol

Conditions
Conditions Yield
With aluminium tris(2,6-diphenylphenoxide); n-butyllithium; diisobutylaluminium hydride; In toluene; at -78 - 25 ℃; for 0.25h; Yields of byproduct given;
99%
3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

isophorol
470-99-5

isophorol

cis-3,3,5-trimethylcyclohexanol
933-48-2

cis-3,3,5-trimethylcyclohexanol

Conditions
Conditions Yield
With sodium tetrahydroborate; activated acidic alumina Brockmann II; In ethyl acetate; at 20 ℃; for 48h; Overall yield = 64 %; Overall yield = 179 mg;

470-99-5 Upstream products

  • 78-59-1
    78-59-1

    3,5,5-Trimethylcyclohex-2-en-1-one

  • 555-31-7
    555-31-7

    aluminum isopropoxide

  • 768-03-6
    768-03-6

    Phenyl vinyl ketone

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    207395-09-3

    (3,5,5-trimethyl-cyclohex-2-enyloxymethyl)-benzene

470-99-5 Downstream products

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    25866-59-5

    1,5,5-trimethylcyclohexa-1,3-diene

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    38313-05-2

    4-nitro-benzoic acid-(3,5,5-trimethyl-cyclohex-2-enyl ester)

  • 25907-92-0
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    5,5-dimethyl-3-methylene-cyclohexene

  • 41169-33-9
    41169-33-9

    3,5,5-trimethylcyclohexa-1,3-diene

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