Chemical plants supply high-quality 3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-OL 470-99-5 in bulk
- Molecular Formula: C9H16O
- Molecular Weight: 140.225
- Appearance/Colour: clear colorless liquid
- Vapor Pressure: 0.161mmHg at 25°C
- Refractive Index: n20/D 1.472(lit.)
- Boiling Point: 188.9 °C at 760 mmHg
- PKA: 14.74±0.60(Predicted)
- Flash Point: 77.9 °C
- PSA: 20.23000
- Density: 0.915 g/cm3
- LogP: 2.11360
3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-OL(Cas 470-99-5) Usage
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Synthesis Reference(s) |
Journal of the American Chemical Society, 100, p. 2226, 1978 DOI: 10.1021/ja00475a040The Journal of Organic Chemistry, 47, p. 3311, 1982 DOI: 10.1021/jo00138a021 |
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General Description |
3,5,5-Trimethyl-2-cyclohexen-1-ol undergoes oxidation in the presence of palladium on activated charcoal under an ethylene atmosphere to yield the corresponding carbonyl compound. |
InChI:InChI=1/C9H16O/c1-7-4-8(10)6-9(2,3)5-7/h4,8,10H,5-6H2,1-3H3/t8-/m1/s1
470-99-5 Relevant articles
Manganese-catalyzed homogeneous hydrogenation of ketones and conjugate reduction of α,β-unsaturated carboxylic acid derivatives: A chemoselective, robust, and phosphine-free in situ-protocol
Topf, Christoph,Vielhaber, Thomas
, (2021/07/10)
We communicate a user-friendly and glove...
BiCl3-Facilitated removal of methoxymethyl-ether/ester derivatives and DFT study of -O-C-O- bond cleavage
Pacherille, Angela,Tuga, Beza,Hallooman, Dhanashree,Dos Reis, Isaac,Vermette, Mélodie,Issack, Bilkiss B.,Rhyman, Lydia,Ramasami, Ponnadurai,Sunasee, Rajesh
supporting information, p. 7109 - 7116 (2021/05/03)
A simple method for the cleavage of meth...
A Practical and Stereoselective In Situ NHC-Cobalt Catalytic System for Hydrogenation of Ketones and Aldehydes
Zhong, Rui,Wei, Zeyuan,Zhang, Wei,Liu, Shun,Liu, Qiang
supporting information, p. 1552 - 1566 (2019/06/14)
Homogeneous catalytic hydrogenation of c...
Cerium-free Luche reduction directed by rehydrated alumina
Jones-Mensah, Ebenezer,Nickerson, Leslie A.,Deobald, Jackson L.,Knox, Hailey J.,Ertel, Alyssa B.,Magolan, Jakob
, p. 3748 - 3753 (2016/06/06)
A 1,2-regioselective reduction of α,β-un...
470-99-5 Process route
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-
768-03-6,26742-84-7
Phenyl vinyl ketone
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-
504-20-1
phorone
-
-
470-99-5
isophorol
| Conditions | Yield |
|---|---|
|
With
aluminium tris(2,6-diphenylphenoxide); n-butyllithium; diisobutylaluminium hydride;
In
toluene;
at -78 - 25 ℃;
for 0.25h;
Yields of byproduct given;
|
99%
|
-
-
78-59-1
3,5,5-Trimethylcyclohex-2-en-1-one
-
-
470-99-5
isophorol
-
-
933-48-2
cis-3,3,5-trimethylcyclohexanol
| Conditions | Yield |
|---|---|
|
With
sodium tetrahydroborate; activated acidic alumina Brockmann II;
In
ethyl acetate;
at 20 ℃;
for 48h;
Overall yield = 64 %; Overall yield = 179 mg;
|
470-99-5 Upstream products
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78-59-1
3,5,5-Trimethylcyclohex-2-en-1-one
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555-31-7
aluminum isopropoxide
-
768-03-6
Phenyl vinyl ketone
-
207395-09-3
(3,5,5-trimethyl-cyclohex-2-enyloxymethyl)-benzene
470-99-5 Downstream products
-
25866-59-5
1,5,5-trimethylcyclohexa-1,3-diene
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38313-05-2
4-nitro-benzoic acid-(3,5,5-trimethyl-cyclohex-2-enyl ester)
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25907-92-0
5,5-dimethyl-3-methylene-cyclohexene
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41169-33-9
3,5,5-trimethylcyclohexa-1,3-diene